Hindered Internal Rotation of N, N-Dimethylpropylamines
نویسندگان
چکیده
منابع مشابه
Hindered rotation in N-methylformamide. A peptide-bond model system.
Barriers to rotation about the C-N bond in the cis and trans isomers of N-methylformamide have been determined by n.m.r. spectroscopy. Representative values are 20.7 and 22.0 kcal/mole. Arrhenius parameters have also been determined. These results are compared with C-N barriers for N,N-dimethylformamide and unsubstituted formamide. The data suggest that C-N rotational barriers for N-methyl amid...
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noindent We have two goals in this paper. First, we investigate and construct cofree coalgebras over $n$-representations of quivers, limits and colimits of $n$-representations of quivers, and limits and colimits of coalgebras in the monoidal categories of $n$-representations of quivers. Second, for any given quivers $mathit{Q}_1$,$mathit{Q}_2$,..., $mathit{Q}_n$, we construct a new quiver $math...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1973
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.21.112